N-tert-butylhydroxylamine → HCID 178441041, compound

HRID 1531239Notes

Reaction equation

HRID 1531239 reaction equation
[C:1]([C:5]1[C:6]([OH:17])=[C:7]([CH:10]=[C:11]([C:13]([CH3:16])([CH3:15])[CH3:14])[CH:12]=1)[CH:8]=O)([CH3:4])([CH3:3])[CH3:2].[C:18]([NH:22][OH:23])([CH3:21])([CH3:20])[CH3:19]>>[C:1]([C:5]1[C:6]([OH:17])=[C:7]([CH:8]=[N+:22]([C:18]([CH3:21])([CH3:20])[CH3:19])[O-:23])[CH:10]=[C:11]([C:13]([CH3:16])([CH3:15])[CH3:14])[CH:12]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 98586N-tert-butylhydroxylamineHCID 6880233,5-Di-tert-butylsalicylaldehyde

Product 1

HCID 178441041HCID 178441041, compound

Procedure

The title compound was prepared according to the procedure described in Example 1 using 3,5-di-tert-butyl-2-hydroxybenzaldehyde and N-tert-butylhydroxylamine. The title compound was isolated in 82.1% yield as a crystalline solid, m.p. 234.7-235.2° C. (Rf=0.66 on a silica gel plate using 1:4 EtOAc/hexanes as an eluant).

Workup

  1. customThe title compound was prepared

Sources & evidence

ORD record
ord-35a5fd3970a34d7c961f08a4925ace66
Source dataset
uspto-grants-2001_03
Patent number
US06197826B1

Reaction notes

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