N-tert-butylhydroxylamine → HCID 178425260, compound

HRID 1531242Notes

Reaction equation

HRID 1531242 reaction equation
[OH:1][C:2]1[C:9]([CH3:10])=[CH:8][CH:7]=[CH:6][C:3]=1[CH:4]=O.[C:11]([NH:15][OH:16])([CH3:14])([CH3:13])[CH3:12]>>[OH:1][C:2]1[C:9]([CH3:10])=[CH:8][CH:7]=[CH:6][C:3]=1[CH:4]=[N+:15]([C:11]([CH3:14])([CH3:13])[CH3:12])[O-:16]

Participants

3

Reactant 2

HCID 98586N-tert-butylhydroxylamineHCID 5227773-Methylsalicylaldehyde

Product 1

HCID 178425260HCID 178425260, compound

Procedure

The title compound was prepared according to the procedure described in Example 9 using 2-hydroxy-3-methylbenzaldehyde and N-tert-butylhydroxylamine. The title compound was isolated in 94% yield as a yellow crystalline solid, m.p. 59.2° C. (Rf=0.71 on a silica gel plate using 1:1 hexanes/EtOAc as an eluant).

Workup

  1. customThe title compound was prepared

Sources & evidence

ORD record
ord-f3e59f4678124d229f512fef5dbd19e3
Source dataset
uspto-grants-2001_03
Patent number
US06197826B1

Reaction notes

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