N-tert-butylhydroxylamine → HCID 178449925, compound

HRID 1531250Notes

Reaction equation

HRID 1531250 reaction equation
[OH:1][C:2]1[CH:9]=[CH:8][C:7]([O:10][C:11]([F:14])([F:13])[F:12])=[CH:6][C:3]=1[CH:4]=O.[C:15]([NH:19][OH:20])([CH3:18])([CH3:17])[CH3:16]>>[OH:1][C:2]1[CH:9]=[CH:8][C:7]([O:10][C:11]([F:14])([F:13])[F:12])=[CH:6][C:3]=1[CH:4]=[N+:19]([C:15]([CH3:18])([CH3:17])[CH3:16])[O-:20]

Participants

3

Reactant 2

HCID 98586N-tert-butylhydroxylamineHCID 12680582-Hydroxy-5-(trifluoromethoxy)benzaldehyde

Product 1

HCID 178449925HCID 178449925, compound

Procedure

The title compound was prepared according to the procedure described in Example 1 using 2-hydroxy-5-trifluoromethoxybenzaldehyde and N-tert-butylhydroxylamine. The title compound was isolated in 81.8% yield as a yellow crystalline solid, m.p. 82.6° C. (Rf=0.40 on a silica gel plate using 7:3 hexanes/EtOAc as an eluant).

Workup

  1. customThe title compound was prepared

Sources & evidence

ORD record
ord-a79f332626924f2fa1e3b0a54fef58ad
Source dataset
uspto-grants-2001_03
Patent number
US06197826B1

Reaction notes

Loading…