Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Chloroaniline | HCID 7932 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | 1,2,3,4-Tetramethylcyclopentadiene | HCID 138163 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 178426071 | HCID 178426071 | — |
Reaction Steps
Sodium hydride (containing mineral oil; the content of sodium hydride: 60%) (0.80 g) and m-chloroaniline (0.064 g) were added to the solution of tetramethylcyclopentadiene (1.34 g; purity: 91.3%; pure compound: 1.22 g) dissolved in tetrahydrofuran (6.73 g), and stirred at 50° C. for one hour. Thus, tetramethylcyclopentadienylsodium was obtained in the form of a solution in tetrahydrofuran.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06197990B1 |
|---|
| Source dataset | uspto-grants-2001_03 |
|---|
| ORD ID | ord-143b36283833404b8440de8070a31160 |
|---|
| Source note | uspto-grants-2001_03 |
|---|
