3-Chloroaniline → HCID 178426071, compound

HRID 1531463Notes

Reaction equation

HRID 1531463 reaction equation
[H-].[Na+:2].ClC1C=C(C=CC=1)N.[CH3:11][C:12]1[CH2:16][C:15]([CH3:17])=[C:14]([CH3:18])[C:13]=1[CH3:19]>O1CCCC1>[CH3:11][C:12]1[CH:16]([Na:2])[C:15]([CH3:17])=[C:14]([CH3:18])[C:13]=1[CH3:19]

Participants

5

Reactant 3

HCID 79323-ChloroanilineHCID 24758Sodium hydride2×HCID 1381631,2,3,4-Tetramethylcyclopentadiene

Product 1

HCID 178426071HCID 178426071, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Conditions

Temperature
50 °C

Procedure

Sodium hydride (containing mineral oil; the content of sodium hydride: 60%) (0.80 g) and m-chloroaniline (0.064 g) were added to the solution of tetramethylcyclopentadiene (1.34 g; purity: 91.3%; pure compound: 1.22 g) dissolved in tetrahydrofuran (6.73 g), and stirred at 50° C. for one hour. Thus, tetramethylcyclopentadienylsodium was obtained in the form of a solution in tetrahydrofuran.

Sources & evidence

ORD record
ord-143b36283833404b8440de8070a31160
Source dataset
uspto-grants-2001_03
Patent number
US06197990B1

Reaction notes

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