HCID 22641069, compound → HCID 17886634, compound

HRID 1532306Notes

Reaction equation

HRID 1532306 reaction equation
[CH3:1][C:2]1([CH3:27])[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2[CH:7]=[C:6]([C:14]#[C:15][S:16][C:17]3[CH:26]=[CH:25][C:20]([C:21]([O:23]C)=[O:22])=[CH:19][CH:18]=3)[CH:5]=[CH:4][C:3]1=2>C1COCC1>[CH3:1][C:2]1([CH3:27])[CH2:11][CH2:10][C:9]([CH3:12])([CH3:13])[C:8]2[CH:7]=[C:6]([C:14]#[C:15][S:16][C:17]3[CH:18]=[CH:19][C:20]([C:21]([OH:23])=[O:22])=[CH:25][CH:26]=3)[CH:5]=[CH:4][C:3]1=2

Participants

3

Reactant 1

HCID 22641069HCID 22641069, compound

Product 1

HCID 17886634HCID 17886634, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

In a manner similar to that of Example 2, by reaction of methyl 4-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-2-naphthylethynylsulphanyl)benzoate in THF, and after crystallization from heptane, the expected derivative is obtained in the form of a white solid.

Workup

  1. customafter crystallization from heptane
  2. customthe expected derivative is obtained in the form of a white solid

Sources & evidence

ORD record
ord-6dce20fbcaaf4aa3b3871ebe437ada1c
Source dataset
uspto-grants-2001_03
Patent number
US06201019B1

Reaction notes

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