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HRID1533832

反应详情

EQUATION

反应方程式

HRID 1533832 的结构方程式

REACTANTS

反应物

2
结构：NOS(=O)(=O)O
HCID76284

Sulfuric acid, monoazanyl ester

H3NO4S

结构：CCCCCCCCCCCCCCCC(=O)C1C(=O)CC(C=O)CC1=O
HCID15003570

未命名化合物

PRODUCTS

生成物

1
结构：CCCCCCCCCCCCCCCC(=O)C1C(=O)CC(C#N)CC1=O
HCID19774689

未命名化合物

收率 86%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O
溶剂HCID962

Water

H2O

2 次

PROCEDURE

实验过程

43 g (0.12 mol) of 5-formyl-2-palmitoylcyclo-hexane-1,3-dione were suspended in 150 ml of distilled water. 15.7 g (0.14 mol) of hydroxylamine-O-sulfonic acid, dissolved in 50 ml of water, were added. The heterogeneous reaction mixture was stirred overnight at room temperature. The solid obtained was filtered off under suction, washed with water and dried. 37.7 g (86% of theory) of 3,5-dioxo-4-palmitoylcyclohexanenitrile of melting point 66-69° C. were isolated.

WORKUP

后处理

  1. additionwere added
  2. customThe solid obtained
  3. filtrationwas filtered off under suction
  4. washwashed with water
  5. customdried