HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanethiol → 3-(1-Methylthiotridecyl)-5-trimethylsilylfuran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanethiol | HCID 878 | — |
| Reactant | 3-(1-Chlorotridecyl)-5-trimethylsilylfuran | HCID 15037076 | — |
| Reactant | Potassium methoxide | HCID 23664618 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 3-(1-Methylthiotridecyl)-5-trimethylsilylfuran | HCID 19909510 | — |
Reaction Steps
A mixture of 3-(1-chlorotridecyl)-5-trimethylsilylfuran, methyl mercaptan and potassium methoxide in tetrahydrofuran is stirred at room temperature to give 3-(1-methylthiotridecyl)-5-trimethylsilylfuran. Oxidizing using Rose Bengal by the procedure of Example 1 gives 4-(1-methylthiotridecyl)-5-hydroxy-2(5H)-furanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05089485 |
| Source dataset | uspto-grants-1992_02 |
| ORD ID | ord-50fa24e29c8b492daa3eb40af4dfcf44 |
| Source note | uspto-grants-1992_02 |