Nitric Acid → Terbium nitrate

HRID 1534924ノート

反応式

HRID 1534924 の反応式
[O-2].[Tb+3:2].[O-2].[O-2].[Tb+3].[N+:6]([O-:9])([OH:8])=[O:7]>>[N+:6]([O-:9])([O-:8])=[O:7].[Tb+3:2].[N+:6]([O-:9])([O-:8])=[O:7].[N+:6]([O-:9])([O-:8])=[O:7]

参加物

3

実験手順

The lanthanum and terbium raw materials may be lanthanum oxide and terbium oxide. Lanthanum oxide is added to concentrated nitric acid to form lanthanum nitrate, which is then preferably diluted. Terbium oxide is added to concentrated nitric acid to form terbium nitrate solution, which is then preferably diluted. The diluted lanthanum nitrate solution and the diluted terbium nitrate solution are then combined to form a single rare earth solution. Hydrated cerium nitrate is then added to the rare earth solution. The molar ratio of the rare earth elements in the rare earth solution is thus about x mole La:y mole Ce:z mole Tb where x=0.39 to 0.73, y=0.17 to 0.45 and z=0.10 to 0.17. The molar ratio of the rare earth elements is preferably about 0.6 mole La:0.225 mole Ce:0.165 mole Tb.

後処理

  1. additionis then preferably diluted

出典と根拠

ORDレコード
ord-c5cbf1d7bd764f16aa74742358bcd439
出典データセット
uspto-grants-1992_02
特許番号
US05091110

反応ノート

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