HCID 54418207, compound → Hydrochloric Acid

HRID 1534986Notes

Reaction equation

HRID 1534986 reaction equation
[ClH:1].CS(SCCN)=[C:4]([OH:6])[OH:5].C(N[C@@:15]1(O)[C@@H:21]([O:22]C(=O)C)[C@H:20](OC(=O)C)[C@@H:19]([CH2:30]OC(=O)C)[O:18][C@H]1S)(=O)C>CO>[ClH:1].[CH3:30][C:19]([CH2:20][C:21]([CH2:15][C:4]([OH:5])=[O:6])=[O:22])=[O:18]

Participants

5

Reactant 2

HCID 54418207HCID 54418207, compoundHCID 88629399HCID 88629399, compound

Product 2

HCID 313Hydrochloric AcidHCID 54598443,5-Dioxohexanoic acid

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

HCl was prepared as follows. To a stirred solution of methyl-2-aminoethylsulfenylthiocarbonate HCl (447 mg, 2.196 mmol) in methanol (5 ml) was added 2-acetamido-3,4,6-tri-O-acetyl-1-thio-β-D-glucose (798 mg, 2.196 mmol) in methanol (10 ml). After stirring at room temperature over night, the mixture was evaporated to dryness yielding the triacetate as a white solid.

Workup

  1. customthe mixture was evaporated to dryness

Sources & evidence

ORD record
ord-416a16a6469b4ab082f79444ea1c22f5
Source dataset
uspto-grants-1992_02
Patent number
US05091523

Reaction notes

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