p-Vinylbenzyl chloride → HCID 19909244, compound

HRID 1535045Notes

Reaction equation

HRID 1535045 reaction equation
[F:1][C:2]([F:29])([F:28])[C:3]([F:27])([O:6][C:7]([F:26])([F:25])[C:8]([C:21]([F:24])([F:23])[F:22])([F:20])[O:9][C:10]([F:19])([F:18])[C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13])[CH2:4][OH:5].Cl[CH2:31][C:32]1[CH:39]=[CH:38][C:35]([CH:36]=[CH2:37])=[CH:34][CH:33]=1>>[F:1][C:2]([F:28])([F:29])[C:3]([F:27])([O:6][C:7]([F:25])([F:26])[C:8]([C:21]([F:24])([F:23])[F:22])([F:20])[O:9][C:10]([F:18])([F:19])[C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13])[CH2:4][O:5][CH2:31][C:32]1[CH:39]=[CH:38][C:35]([CH:36]=[CH2:37])=[CH:34][CH:33]=1

Participants

3

Reactant 2

HCID 74126p-Vinylbenzyl chlorideHCID 27361501H,1H-Perfluoro-2,5-dimethyl-3,6-dioxanonan-1-ol

Product 1

HCID 19909244HCID 19909244, compoundYield 70.2%

Procedure

As in Example 1, 96.4 grams (0.2 mol) of 2,5-bis-trifluoromethyl-2,4,4,5,7,7,8,8,9,9,9-undecafluoro-3,6-dioxanonanol was reacted with 30.6 grams (0.2 mol) of p-chloromethylstyrene, yielding as a fraction at 96°-97° C. and 1.4×10-4 mmHg 84 grams (yield 70%) of p-(4,7-bistrifluoromethyl-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-2,5,8-trioxaundecyl)styrene. ##STR13##

Workup

  1. customyielding as a fraction at 96°-97° C.

Sources & evidence

ORD record
ord-2897af1968034925bf22647ceb059aa9
Source dataset
uspto-grants-1992_02
Patent number
US05091588

Reaction notes

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