HuagongsheHuagongshe Chemistry Print Report · For research reference only
(5-Methoxy-1-benzofuran-2-yl)methanol → 2-Benzofurancarboxaldehyde, 5-methoxy-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (5-Methoxy-1-benzofuran-2-yl)methanol | HCID 15161064 | — |
| Catalyst | Manganese dioxide | HCID 14801 | — |
| Product | 2-Benzofurancarboxaldehyde, 5-methoxy- | HCID 31663 | 60% |
Reaction Steps
To a solution of 5-methoxy-2-hydroxymethylbenzofuran (16.0 gm; 90 mmoles) in ethyl acetatel (1 L) was added MnO2 (78 gm, 900 mmoles). The reaction mixture was stirred at room temperature for 3 hours. Then this suspension was filtered through celite and concentrate in vacuo. The filtrate yielded the title Compound E9, (9.5 gm, 60%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05091533 |
| Source dataset | uspto-grants-1992_02 |
| ORD ID | ord-69234d5c0ede43d9b79317bf3c16241d |
| Source note | uspto-grants-1992_02 |