Bicarbonate Ion → N-ethoxalyl-2-formyltetrahydroquinoline

HRID 1535700Notes

Reaction equation

HRID 1535700 reaction equation
[C:1](=[O:2])([C:3](=[O:4])[O:5][CH2:6][CH3:7])[N:8]1[CH:9]([CH2:18][O:19][Si:20]([CH3:21])([CH3:22])[CH3:23])[CH2:10][CH2:11][CH:12]2[CH2:13][CH:14]=[CH:15][CH:16]=[C:17]12.[C:38](=[O:39])([OH:40])[O-:41].[Cl:43][CH2:44][Cl:45].[Na+:36].[Na+:37].[Na+:42].[OH:24][C:25]([C:26]([F:27])([F:28])[F:29])=[O:30].[S:31]([O-:32])([O-:33])(=[O:34])=[S:35]>>[C:1](=[O:2])([C:3](=[O:4])[O:5][CH2:6][CH3:7])[N:8]1[CH:9]([CH:18]=[O:19])[CH2:10][CH2:11][CH:12]2[CH2:13][CH:14]=[CH:15][CH:16]=[C:17]12

Participants

7

Reactant 6

HCID 769Bicarbonate IonHCID 923Sodium ion3×HCID 1084Thiosulfate ionHCID 6344DichloromethaneHCID 6422Trifluoroacetic acidHCID 67722031N-ethoxalyl-2-trimethylsilyloxymethyltetrahydroquinoline

Product 1

HCID 86750625N-ethoxalyl-2-formyltetrahydroquinoline

Sources & evidence

ORD record
ord-9461b55684734e9aa444e48a9217176e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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