HRID1544159

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID813

Potassium cation

K+

HCID8028

Tetrahydrofuran

C4H8O

HCID30165

Iodide ion

I-

反应SMILES：C[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID74506

Triphenylmethylphosphonium

C19H18P+

HCID4574913

未命名化合物

反应SMILES：C[Si](C)(C)CCOCn1ccc2c(-c3cnn(C(CC=O)c4cccc(Br)c4)c3)ncnc21

HCID57478002

未命名化合物

PRODUCTS

产物

反应SMILES：C=CCC(c1cccc(Br)c1)n1cc(-c2ncnc3c2ccn3COCC[Si](C)(C)C)cn1

HCID57480688

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-0308c1eb439d4b3490329ccfda99ba9b
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应SMILES

[Br:28][c:29]1[cH:30][c:31]([CH:35]([CH2:36][CH:37]=[O:38])[n:39]2[n:40][cH:41][c:42](-[c:44]3[c:45]4[c:46]([n:47][cH:48][n:49]3)[n:50]([CH2:53][O:54][CH2:55][CH2:56][Si:57]([CH3:58])([CH3:59])[CH3:60])[cH:51][cH:52]4)[cH:43]2)[cH:32][cH:33][cH:34]1.[CH2:61]1[O:62][CH2:63][CH2:64][CH2:65]1.[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:8][P+:9]([c:10]1[cH:11][cH:12][cH:13][cH:14][cH:15]1)([c:16]1[cH:17][cH:18][cH:19][cH:20][cH:21]1)[c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1.[I-:7].[K+:6]>>[CH2:1]=[CH:37][CH2:36][CH:35]([c:31]1[cH:30][c:29]([Br:28])[cH:34][cH:33][cH:32]1)[n:39]1[n:40][cH:41][c:42](-[c:44]2[c:45]3[c:46]([n:47][cH:48][n:49]2)[n:50]([CH2:53][O:54][CH2:55][CH2:56][Si:57]([CH3:58])([CH3:59])[CH3:60])[cH:51][cH:52]3)[cH:43]1