Methyl chloroformate → 3-Methoxy-9-(4-methoxy-phenyl)-4b,5,6,7,8,8a,9,10-octahydro-phenanthrene-2-carboxylic acid methyl ester

HRID 1544467Notes

Reaction equation

HRID 1544467 reaction equation
[Br:1][c:2]1[c:3]([O:24][CH3:25])[cH:4][c:5]2[c:14]([cH:15]1)[CH2:13][CH:12]([c:16]1[cH:17][cH:18][c:19]([O:22][CH3:23])[cH:20][cH:21]1)[CH:11]1[CH:6]2[CH2:7][CH2:8][CH2:9][CH2:10]1.[C:26]([Li:27])([CH3:28])([CH3:29])[CH3:30].[Cl:31][C:32](=[O:33])[O:34][CH3:35].[O:36]1[CH2:37][CH2:38][CH2:39][CH2:40]1>>[c:2]1([C:32](=[O:33])[O:34][CH3:35])[c:3]([O:24][CH3:25])[cH:4][c:5]2[c:14]([cH:15]1)[CH2:13][CH:12]([c:16]1[cH:17][cH:18][c:19]([O:22][CH3:23])[cH:20][cH:21]1)[CH:11]1[CH:6]2[CH2:7][CH2:8][CH2:9][CH2:10]1

Participants

5

Reactant 4

HCID 6586Methyl chloroformateHCID 8028TetrahydrofuranHCID 666520557-Bromo-6-methoxy-10-(4-methoxy-phenyl)-1,2,3,4,4a,9,10,10a-octahydro-phenanthreneHCID 178418306HCID 178418306, compound

Product 1

HCID 666521243-Methoxy-9-(4-methoxy-phenyl)-4b,5,6,7,8,8a,9,10-octahydro-phenanthrene-2-carboxylic acid methyl ester

Sources & evidence

ORD record
ord-7044ac701afa45989b6b8ecc75699ac3
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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