Bicarbonate Ion → 6-Hydroxymethyl-4-(4-triisopropylsilanyloxybutyl)-4H-benzo[1,4]oxazin-3-one

HRID 1549080Notes

Reaction equation

HRID 1549080 reaction equation
[Br:16][CH2:17][CH2:18][CH2:19][CH2:20][O:21][Si:22]([CH:23]([CH3:24])[CH3:25])([CH:26]([CH3:27])[CH3:28])[CH:29]([CH3:30])[CH3:31].[CH3:37][N:38]([CH3:39])[CH:40]=[O:41].[H-:14].[Na+:15].[Na+:32].[OH:1][CH2:2][c:3]1[cH:4][cH:5][c:6]2[c:7]([cH:13]1)[NH:8][C:9](=[O:12])[CH2:10][O:11]2.[OH:33][C:34](=[O:35])[O-:36]>>[OH:1][CH2:2][c:3]1[cH:4][cH:5][c:6]2[c:7]([cH:13]1)[N:8]([CH2:17][CH2:18][CH2:19][CH2:20][O:21][Si:22]([CH:23]([CH3:24])[CH3:25])([CH:26]([CH3:27])[CH3:28])[CH:29]([CH3:30])[CH3:31])[C:9](=[O:12])[CH2:10][O:11]2

Participants

7

Reactant 6

HCID 769Bicarbonate IonHCID 923Sodium ion2×HCID 6228DimethylformamideHCID 166653HydrideHCID 184524436-(Hydroxymethyl)-2H-1,4-benzoxazin-3(4H)-oneHCID 86610030(4-Bromobutoxy)triisopropylsilane

Product 1

HCID 685022706-Hydroxymethyl-4-(4-triisopropylsilanyloxybutyl)-4H-benzo[1,4]oxazin-3-one

Sources & evidence

ORD record
ord-a28f6294a08d498a83428593d7f4d577
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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