Potassium Cation → 3-Propoxypicolinaldehyde

HRID 1555619Notes

Reaction equation

HRID 1555619 reaction equation
[C:26]([CH:27]([CH:28]([C:29]([O-:30])=[O:31])[OH:32])[OH:33])([O-:34])=[O:35].[CH2:1]([CH2:3][CH3:16])[O:4][C:5](=[O:2])[c:6]1[c:7]([O:12][CH2:13][CH2:14][CH3:15])[cH:8][cH:9][cH:10][n:11]1.[CH3:17][CH:18]([CH2:19][AlH:20][CH2:21][CH:22]([CH3:23])[CH3:24])[CH3:25].[Cl:38][CH2:39][Cl:40].[K+:36].[Na+:37].[O:41]=[Mn:42]=[O:43]>>[O:4]=[CH:5][c:6]1[c:7]([O:12][CH2:13][CH2:14][CH3:15])[cH:8][cH:9][cH:10][n:11]1

Participants

8

Reactant 7

HCID 813Potassium CationHCID 923Sodium ionHCID 6344DichloromethaneHCID 14487Diisobutylaluminum hydrideHCID 14801Manganese dioxideHCID 38061142,3-DihydroxybutanedioateHCID 19756120Propyl 3-Propoxypyridine-2-carboxylate

Product 1

HCID 220188513-Propoxypicolinaldehyde

Sources & evidence

ORD record
ord-766db967edcc4926ad1a22a9198dc981
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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