HRID1557447

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11776

Triphenylphosphine

C18H15P

2 次

HCID24290

未命名化合物

结构：CCOC(=O)C1(c2ccc(B3OC(C)(C)C(C)(C)O3)cc2)CC1

HCID53217182

Ethyl 1-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropane-1-carboxylate

C18H25BO4

HCID66582118

未命名化合物

PRODUCTS

生成物

结构：C=CC(C)C(O)c1c(C)noc1-c1ccc(-c2ccc(C3(C(=O)OCC)CC3)cc2)cc1

HCID66577384

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1c75b33c2cb14c9ab14bda15d1c9d3b9
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[Br:1][c:2]1[cH:3][cH:4][c:5](-[c:8]2[c:9]([CH:14]([CH:15]([CH:16]=[CH2:17])[CH3:18])[OH:19])[c:10]([CH3:13])[n:11][o:12]2)[cH:6][cH:7]1.[CH2:20]([CH3:21])[O:22][C:23](=[O:24])[C:25]1([c:28]2[cH:29][cH:30][c:31]([B:34]3[O:35][C:36]([CH3:37])([CH3:38])[C:39]([CH3:40])([CH3:41])[O:42]3)[cH:32][cH:33]2)[CH2:26][CH2:27]1.[Pd:43]([Cl:44])[Cl:45].[c:46]1([P:47]([c:48]2[cH:49][cH:50][cH:51][cH:52][cH:53]2)[c:54]2[cH:55][cH:56][cH:57][cH:58][cH:59]2)[cH:60][cH:61][cH:62][cH:63][cH:64]1.[c:65]1([P:66]([c:67]2[cH:68][cH:69][cH:70][cH:71][cH:72]2)[c:73]2[cH:74][cH:75][cH:76][cH:77][cH:78]2)[cH:79][cH:80][cH:81][cH:82][cH:83]1>>[c:2]1(-[c:31]2[cH:30][cH:29][c:28]([C:25]3([C:23]([O:22][CH2:20][CH3:21])=[O:24])[CH2:26][CH2:27]3)[cH:33][cH:32]2)[cH:3][cH:4][c:5](-[c:8]2[c:9]([CH:14]([CH:15]([CH:16]=[CH2:17])[CH3:18])[OH:19])[c:10]([CH3:13])[n:11][o:12]2)[cH:6][cH:7]1