Acetate → 1-(1H-inden-2-yl)-1H-pyrrole

HRID 1557724Notes

Reaction equation

HRID 1557724 reaction equation
[Br:9][C:10]1=[CH:18][c:17]2[c:12]([cH:13][cH:14][cH:15][cH:16]2)[CH2:11]1.[C:24]([P:25]([C:26]([CH3:27])([CH3:28])[CH3:29])[c:30]1[cH:31][cH:32][cH:33][cH:34][c:35]1-[c:36]1[cH:37][cH:38][cH:39][cH:40][cH:41]1)([CH3:42])([CH3:43])[CH3:44].[CH3:45][c:46]1[cH:47][cH:48][cH:49][cH:50][cH:51]1.[CH3:52][O:53][CH2:54][CH2:55][O:56][CH3:57].[K+:6].[K+:7].[K+:8].[O-:59][C:60]([CH3:61])=[O:62].[O-:63][C:64]([CH3:65])=[O:66].[P:1]([O-:2])([O-:3])([O-:4])=[O:5].[Pd+2:58].[nH:19]1[cH:20][cH:21][cH:22][cH:23]1>>[C:10]1([n:19]2[cH:20][cH:21][cH:22][cH:23]2)=[CH:18][c:17]2[c:12]([cH:13][cH:14][cH:15][cH:16]2)[CH2:11]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 813Potassium Cation3×HCID 1061PhosphateHCID 1140TolueneHCID 8027PyrroleHCID 80711,2-DimethoxyethaneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 5755861H-Indene, 2-bromo-HCID 27342152-(Di-tert-butylphosphino)biphenyl

Product 1

HCID 180083501-(1H-inden-2-yl)-1H-pyrrole

Sources & evidence

ORD record
ord-4e186c7e3f42486ab641aa31d2c64e99
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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