Chlorotrimethylsilane → HCID 178423718, compound

HRID 15700Notes

Reaction equation

HRID 15700 reaction equation
C[N-]C.C[N-]C.[CH3:7][C:8]1[CH:9]([C:16]2[CH:24]=[CH:23][CH:22]=[CH:21][C:17]=2[CH2:18][O:19][Ti+2:20])[C:10]([CH3:15])=[C:11]([CH3:14])[C:12]=1[CH3:13].C[Si](C)(C)[Cl:27]>CCCCC>[Cl-:27].[Cl-:27].[CH3:15][C:10]1[CH:9]([C:16]2[CH:24]=[CH:23][CH:22]=[CH:21][C:17]=2[CH2:18][O:19][Ti+2:20])[C:8]([CH3:7])=[C:12]([CH3:13])[C:11]=1[CH3:14]

Participants

4

Reactant 2

HCID 6397ChlorotrimethylsilaneHCID 178423719HCID 178423719, compound

Product 1

HCID 178423718HCID 178423718, compoundYield 94.3%

Reagents, catalysts & solvents 1

HCID 8003PentaneSolvent2×

Procedure

To a solution of 2-(2,3,4,5-tetramethylcyclopentadienyl)benzyloxytitanium bis(dimethylamide) (0.84 g, 3.1 mmol) in pentane (15.2 mL) was added dropwise a solution of trimethylchlorosilane (3.67 g, 33.8 mmol) in pentane (5.0 mL) at 0° C. The mixture was stirred at room temperature for 15 hrs. 2-(2,3,4,5-Tetramethylcyclopentadienyl)benzyloxytitanium dichloride (1.00 g, yield 94.3%) was obtained as an yellow solid.

Sources & evidence

ORD record
ord-b20b010652fc418eba1980d99ba1f664
Source dataset
uspto-grants-2010_06
Patent number
US07732643B2

Reaction notes

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