HRID1570200

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID1140

Toluene

C7H8

HCID28486

Lithium ion

Li+

HCID104727

Aluminum Cation

Al+3

HCID166653

Hydride

H-

4 次

结构：CC(C)[P+]1(C(C)C)Cc2ccc3ccccc3c2-c2c(ccc3ccccc23)C1

HCID18929265

未命名化合物

PRODUCTS

生成物

结构：Cc1ccc2ccccc2c1-c1c(CP(C(C)C)C(C)C)ccc2ccccc12

HCID19690361

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-168854393117486285dc40614c95b260
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[Al+3:32].[Br-:1].[CH3:37][c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1.[CH:2]([CH3:3])([CH3:4])[P+:5]1([CH:28]([CH3:29])[CH3:30])[CH2:6][c:7]2[c:8]([c:20]3[cH:21][cH:22][cH:23][cH:24][c:25]3[cH:26][cH:27]2)-[c:9]2[c:10]([cH:12][cH:13][c:14]3[cH:15][cH:16][cH:17][cH:18][c:19]23)[CH2:11]1.[H-:31].[H-:34].[H-:35].[H-:36].[Li+:33]>>[CH:2]([CH3:3])([CH3:4])[P:5]([CH2:6][c:7]1[c:8](-[c:9]2[c:10]([CH3:11])[cH:12][cH:13][c:14]3[cH:15][cH:16][cH:17][cH:18][c:19]23)[c:20]2[cH:21][cH:22][cH:23][cH:24][c:25]2[cH:26][cH:27]1)[CH:28]([CH3:29])[CH3:30]