Acetate → 4-Ethoxy-6-formyl-quinoline-3-carbonitrile

HRID 1572455Notes

Reaction equation

HRID 1572455 reaction equation
[CH2:1]([CH3:2])[O:3][c:4]1[c:5]([C:15]#[N:16])[cH:6][n:7][c:8]2[cH:9][cH:10][c:11]([I:14])[cH:12][c:13]12.[CH2:33]([SiH:34]([CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40])[CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH3:46])[CH2:47][CH2:48][CH2:49][CH2:50][CH3:51].[CH3:52][N:53]([CH:54]=[O:55])[CH3:56].[O-:58][C:59]([CH3:60])=[O:61].[O-:62][C:63]([CH3:64])=[O:65].[Pd+2:57].[c:17]1([CH:18]([c:19]2[cH:20][cH:21][cH:22][cH:23][cH:24]2)[CH2:25][CH2:26][PH2:27])[cH:28][cH:29][cH:30][cH:31][cH:32]1>>[CH2:1]([CH3:2])[O:3][c:4]1[c:5]([C:15]#[N:16])[cH:6][n:7][c:8]2[cH:9][cH:10][c:11]([CH:54]=[O:55])[cH:12][c:13]12

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6228DimethylformamideHCID 76231CID 76231HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 53436545Diphenylpropyl phosphineHCID 58585794HCID 58585794, compound

Product 1

HCID 585858184-Ethoxy-6-formyl-quinoline-3-carbonitrile

Sources & evidence

ORD record
ord-07b8404247c94bdcac325ff39fab9045
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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