HRID1572938

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID962

Water

H2O

HCID8028

Tetrahydrofuran

C4H8O

HCID8058

n-Hexane

C6H14

结构：CCCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID2724566

PENTYL-TRIPHENYL-PHOSPHANIUM

C23H26P+

HCID19363379

未命名化合物

HCID178418339

未命名化合物

PRODUCTS

生成物

HCID54162305

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-97d5009070294a91bf0991287c0fc2c7
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[Br-:1].[CH2:2]([CH2:3][CH2:4][CH2:5][CH3:6])[P+:7]([c:8]1[cH:9][cH:10][cH:11][cH:12][cH:13]1)([c:14]1[cH:15][cH:16][cH:17][cH:18][cH:19]1)[c:20]1[cH:21][cH:22][cH:23][cH:24][cH:25]1.[CH2:32]([Li:33])[CH2:34][CH2:35][CH3:36].[CH2:55]1[O:56][CH2:57][CH2:58][CH2:59]1.[CH3:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31].[CH3:37][C:38]1([CH3:53])[N:39]=[C:40]([c:43]2[cH:44][cH:45][c:46]([O:51][CH3:52])[c:47]([CH:48]=[O:49])[cH:50]2)[O:41][CH2:42]1.[OH2:54]>>[CH:2]([CH2:3][CH2:4][CH2:5][CH3:6])=[CH:48][c:47]1[c:46]([O:51][CH3:52])[cH:45][cH:44][c:43]([C:40]2=[N:39][C:38]([CH3:37])([CH3:53])[CH2:42][O:41]2)[cH:50]1