Methanol → HCID 53810175, compound

HRID 1576009Notes

Reaction equation

HRID 1576009 reaction equation
[NH4+].[Cl:2][C:3]1[C:4]([C:15]#[N:16])=[C:5]([C:9]([Cl:14])=[C:10](Cl)[C:11]=1[Cl:12])[C:6]([O-:8])=[O:7].[CH3:17][O-:18].[Na+].[CH3:20]O>CN(C)C=O>[CH3:20][O:8][C:6](=[O:7])[C:5]1[C:9]([Cl:14])=[C:10]([O:18][CH3:17])[C:11]([Cl:12])=[C:3]([Cl:2])[C:4]=1[C:15]#[N:16]

Participants

5

Reactant 3

HCID 887MethanolHCID 10942334Sodium MethoxideHCID 46846345HCID 46846345, compound

Product 1

HCID 53810175HCID 53810175, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

30.2 g of 3,4,5,6-tetrachloro-2-cyanobenzoic acid ammonium salt is introduced, with stirring, into a solution of 10.8 g of sodium methylate in 32 ml of methanol and 100 ml of dimethylformamide. After the slightly exothermic reaction has subsided, stirring is continued for 15 hours at room temperature.

Workup

  1. customAfter the slightly exothermic reaction

Sources & evidence

ORD record
ord-af9884bbe1f9489f9f7766faa04e62c4
Source dataset
uspto-grants-1976_09
Patent number
US03979386

Reaction notes

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