1,2-Ethanedisulfenyl dichloride → HCID 21513871, compound

HRID 1576080Notes

Reaction equation

HRID 1576080 reaction equation
[CH2:1]([S:5]Cl)[CH2:2][S:3]Cl.[CH2:7]([NH:14][C:15](=[S:17])[S-:16])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.[Na+]>>[CH2:7]([NH:14][C:15]([S:16][S:3][CH2:2][CH2:1][S:5][S:17][C:15](=[S:16])[NH:14][CH2:7][C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)=[S:17])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1

Participants

3

Reactant 2

HCID 118160341,2-Ethanedisulfenyl dichlorideHCID 23686905Carbamic acid, benzyldithio-, monosodium salt

Product 1

HCID 21513871HCID 21513871, compound

Procedure

Bis-dithiocarbamates from primary amines are similarly prepared. For example, addition of 1,2-ethanedisulfenyl chloride solution to an aqueous solution of sodium benzyldithiocarbamate gives nearly a quantitative yield of 1,2-bis(N-benzylthiocarbamoyldithio)ethane, m.p. 105°-110°C, decom., NMR 7.3 singlet, 4.9 mult., 3.4 singlet and 3.15 singlet.

Sources & evidence

ORD record
ord-2de71e0804df452cac0a876e5978f145
Source dataset
uspto-grants-1976_09
Patent number
US03979369

Reaction notes

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