Sodium Hydroxide → AE-848/34436008

HRID 1576657Notes

Reaction equation

HRID 1576657 reaction equation
Cl.[CH3:2][C:3]1([CH3:26])[CH2:8][CH:7]([NH:9][C:10](=[O:23])[C:11]2[CH:16]=[C:15]([N+:17]([O-:19])=[O:18])[CH:14]=[C:13]([N+:20]([O-:22])=[O:21])[CH:12]=2)[CH2:6][C:5]([CH3:25])([CH3:24])[NH:4]1.[OH-].[Na+]>O>[CH3:24][C:5]1([CH3:25])[CH2:6][CH:7]([NH:9][C:10](=[O:23])[C:11]2[CH:12]=[C:13]([N+:20]([O-:22])=[O:21])[CH:14]=[C:15]([N+:17]([O-:19])=[O:18])[CH:16]=2)[CH2:8][C:3]([CH3:26])([CH3:2])[NH:4]1

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 21511588HCID 21511588, compound

Product 1

HCID 3139336AE-848/34436008Yield 84%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

N-(2,2,6,6-Tetramethyl-4-piperidyl)-3,5-dinitrobenzamide hydrochloride (18.5 g.) is dissolved in water (350 ml.) and the pH adjusted to 11 with 1.0N NaOH. A cream colored precipitate forms and is collected by filtration, washed with water and dried (14.1 g., m.p. 220°-222°, 84% yield).

Workup

  1. filtrationis collected by filtration
  2. washwashed with water
  3. customdried (14.1 g., m.p. 220°-222°, 84% yield)

Sources & evidence

ORD record
ord-c43a991c4e93418fa9ef70db2203bc21
Source dataset
uspto-grants-1976_09
Patent number
US03982006

Reaction notes

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