化工社化工社 化学情報印刷レポート · 研究参考用
Water → 4-(Benzyloxy)benzoic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Sulfuric Acid | HCID 1118 | — |
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Benzyl p-tolyl ether | HCID 70036 | — |
| 溶媒 | Sodium Dichromate | HCID 25408 | — |
| 生成物 | 4-(Benzyloxy)benzoic acid | HCID 73880 | — |
反応手順
A mixture of 4-methylphenoxy phenyl methane (2g) was suspended in aqueous sodium dichromate solution (20ml. 50%) and concentrated sulphuric acid (10ml) added dropwise with stirring. The mixture was stirred at room temperature overnight then warmed on a water bath for 1hr. The mixture was cooled, diluted with water and the 4-carboxyphenoxy phenyl methane (m.p. 188°) isolated with ether.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03983164 |
| 出典データセット | uspto-grants-1976_09 |
| ORD ID | ord-5a0876f291b946d594ae1bf223fd95ba |
| 出典メモ | uspto-grants-1976_09 |