Piperidine → 2,7-Bis(piperidinocarbonyl)fluoren-9-one

HRID 1576967Notes

Reaction equation

HRID 1576967 reaction equation
[NH:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH2:7](NCC=C)[CH:8]=C.C(N(CC)[C:17]([C:19]1[CH:31]=[CH:30][C:29]2[C:28]3[C:23](=[CH:24][C:25]([C:32]([N:34]([CH2:37]C)[CH2:35][CH3:36])=[O:33])=[CH:26][CH:27]=3)[C:22](=[O:39])[C:21]=2[CH:20]=1)=[O:18])C>>[N:1]1([C:17]([C:19]2[CH:31]=[CH:30][C:29]3[C:28]4[C:23](=[CH:24][C:25]([C:32]([N:34]5[CH2:37][CH2:8][CH2:7][CH2:36][CH2:35]5)=[O:33])=[CH:26][CH:27]=4)[C:22](=[O:39])[C:21]=3[CH:20]=2)=[O:18])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

4

Reactant 3

HCID 8082PiperidineHCID 31279DiallylamineHCID 21509986HCID 21509986, compound

Product 1

HCID 215099982,7-Bis(piperidinocarbonyl)fluoren-9-one

Procedure

Substituting an equivalent molar amount of piperidine or diallylamine in lieu of the diethylamine above, results in the formation of 2,7-bis(piperidinocarbonyl)fluoren-9-one m.p. 255.5°C; and N,N,N',N'-tetraallyl-9-oxo-fluorene-2,7-dicarboxamide, m.p. 94.5°-95.5°C,

Sources & evidence

ORD record
ord-9b77423e82de4be4aaf2c08308a63e81
Source dataset
uspto-grants-1976_09
Patent number
US03983124

Reaction notes

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