Nitrosyl chloride → HCID 3303868, compound

HRID 1576985Notes

Reaction equation

HRID 1576985 reaction equation
[CH3:1][C:2]1[CH:10]=[CH:9][C:5]([CH:6]=[N:7][OH:8])=[CH:4][CH:3]=1.N([Cl:13])=O>CCOCC>[CH3:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([Cl:13])=[N:7][OH:8])=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 17601Nitrosyl chlorideHCID 19475HCID 19475, compound

Product 1

HCID 3303868HCID 3303868, compoundYield 35.4%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

By the method of Example I-B, 67.6 g of 4-methylbenzaldoxime in 600 ml of ether was treated with 39.3 g of nitrosyl chloride. After removal of the ether, the product was recrystallized twice from hexane to give 30 g of 4-methylbenzohydroximoyl chloride, m.p. 70°-73°.

Workup

  1. customAfter removal of the ether
  2. customthe product was recrystallized twice from hexane

Sources & evidence

ORD record
ord-aef5f21b8b30495c9670aac3a9091895
Source dataset
uspto-grants-1976_09
Patent number
US03983246

Reaction notes

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