Ammonium Acetate → HCID 178510717, compound

HRID 1577557Notes

Reaction equation

HRID 1577557 reaction equation
[C:1]([C:9]1[S:13][C:12]2[CH:14]=[CH:15][CH:16]=[CH:17][C:11]=2[C:10]=1[OH:18])(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[NH4+:23]>>[NH2:23]/[C:1](/[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[C:9]1\[C:10](=[O:18])[C:11]2[CH:17]=[CH:16][CH:15]=[CH:14][C:12]=2[S:13]\1

Participants

3

Reactant 2

HCID 517165Ammonium AcetateHCID 4712192Methanone, (3-hydroxybenzo[b]thien-2-yl)phenyl-

Product 1

HCID 178510717HCID 178510717, compound

Procedure

When 2-benzoyl-benzo[b]thiophen-3-ol was reacted with the following reagents instead of with ammonium acetate under the conditions of Example 31, the title compound, m.p. 121°-122° C. (petroleum ether/ethyl acetate 2:1), was obtained with the yields given to the right below:

Sources & evidence

ORD record
ord-551bf2d76b9f4c3c9036a0b8dec60dea
Source dataset
uspto-grants-1981_09
Patent number
US04288437

Reaction notes

Loading…