Ammonium Acetate → HCID 178422569, compound

HRID 1577563Notes

Reaction equation

HRID 1577563 reaction equation
[C:1]([C:9]1[S:13][C:12]2[CH:14]=[C:15]([CH3:18])[CH:16]=[CH:17][C:11]=2[C:10]=1[OH:19])(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[NH4+:24]>>[NH2:24]/[C:1](/[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[C:9]1\[C:10](=[O:19])[C:11]2[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][C:12]=2[S:13]\1

Participants

3

Reactant 2

HCID 517165Ammonium AcetateHCID 136195700HCID 136195700, compound

Product 1

HCID 178422569HCID 178422569, compoundYield 57%

Procedure

Prepared as in Example 31 from 2-benzoyl-6-methyl-benzo[b]thiophen-3-ol and ammonium acetate with a yield of 57% of theory. M.p. 166°-167° C. (ethyl acetate/petroleum ether 1:1).

Sources & evidence

ORD record
ord-52236200210e47439aaf9a32d6264d08
Source dataset
uspto-grants-1981_09
Patent number
US04288437

Reaction notes

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