Ammonium Acetate → HCID 178423598, compound

HRID 1577565Notes

Reaction equation

HRID 1577565 reaction equation
[C:1]([C:9]1[S:13][C:12]2[CH:14]=[CH:15][CH:16]=[C:17]([CH3:18])[C:11]=2[C:10]=1[OH:19])(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[NH4+:24].C(OC(C)C)(C)C.C(OCC)(=O)C>>[NH2:24]/[C:1](/[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[C:9]1\[C:10](=[O:19])[C:11]2[C:17]([CH3:18])=[CH:16][CH:15]=[CH:14][C:12]=2[S:13]\1

Participants

4

Reactant 3

HCID 517165Ammonium AcetateHCID 22281796Diisopropylether ethyl acetateHCID 136139896HCID 136139896, compound

Product 1

HCID 178423598HCID 178423598, compoundYield 50%

Procedure

Prepared as in Example 31 from 2-benzoyl-4-methyl-benzo[b]thiophen-3-ol and ammonium acetate with a yield of 50% of theory. M.p. 198°-200° C. (diisopropyl ether/ethyl acetate 2:1).

Sources & evidence

ORD record
ord-a3fc25c63a7a41aab2064312785e2139
Source dataset
uspto-grants-1981_09
Patent number
US04288437

Reaction notes

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