Acrylamide → Acrylamide

HRID 1577617Notes

Reaction equation

HRID 1577617 reaction equation
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([NH2:10])(=[O:9])[CH:7]=[CH2:8].[C:11]([O:15][CH2:16][CH:17]([OH:19])[CH3:18])(=[O:14])[CH:12]=[CH2:13].S(OOS([O-])(=O)=O)([O-])(=O)=O.[NH4+].[NH4+].S([O-])(OCCCCCCCCCCCC)(=O)=O.[Na+:49].[OH-].[Na+]>CO.CC(C)=O>[C:1]([O-:5])(=[O:4])[CH:2]=[CH2:3].[Na+:49].[C:11]([O:15][CH2:16][CH:17]([OH:19])[CH3:18])(=[O:14])[CH:12]=[CH2:13].[C:6]([NH2:10])(=[O:9])[CH:7]=[CH2:8]

Participants

10

Reactant 6

HCID 6579AcrylamideHCID 6581Acrylic AcidHCID 14798Sodium HydroxideHCID 612492-Hydroxypropyl acrylateHCID 62648Ammonium PersulfateHCID 3423265Sodium Lauryl Sulfate

Product 2

HCID 6579AcrylamideHCID 86737734Sodium acrylate 2-hydroxypropyl acrylate

Reagents, catalysts & solvents 2

HCID 180AcetoneSolventHCID 887MethanolSolvent

Procedure

A terpolymer of sodium acrylate-2-hydroxypropyl acrylate and acrylamide was prepared utilizing an emulsion polymerization process. The mole ratios of acrylic acid to acrylamide, mole percent of 2-hydroxypropyl acrylate and molecular size were varied by controlling the reaction parameters. Six representative samples of the terpolymer were prepared with the compositions of the various terpolymers being estimated based upon their total nitrogen content. In the reaction, ammonium persulfate was utilized as the polymerization initiator or catalyst. Reagent grade acetone and reagent grade anhydrous methanol were utilized to form the solvent. The emulsifier was sodium lauryl sulfate, and 2 N aqueous sodium hydroxide was utilized to neutralize the reactants. The dried products were thereafter milled and passed through a number 30 mesh screen. The reaction was conducted over a period of three hours at a reaction temperature of about 60° C.

Workup

  1. customan emulsion polymerization process
  2. customthe reaction parameters
  3. customSix representative samples of the terpolymer were prepared with the compositions of the various terpolymers
  4. customto form the solvent
  5. customThe dried products were thereafter milled

Sources & evidence

ORD record
ord-63cf7005e49e464fac0afefac37c1e1a
Source dataset
uspto-grants-1981_09
Patent number
US04288582

Reaction notes

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