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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1577654Generated: November 4, 2026

Ethyl diazoacetate → Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, ethyl ester

https://huagongshe.com/reaction/1577654

Reaction equation

Participants

RoleNameHCIDCharge
ReactantEthyl diazoacetateHCID 12192—
Reactant1,3-Pentadiene, 1,1-dichloro-4-methyl-HCID 108746—
CatalystCopper SulfateHCID 24462—
ProductCyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, ethyl esterHCID 101094—

Reaction Steps

Thus, for example, in Pesticide Science (1974) 5, 791-799 it is shown that the reaction between ethyl diazoacetate and 1,1-dichloro-4-methylpenta-1,3-diene in the presence of copper sulfate to produce ethyl 2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropanecarboxylate, results in a product which is contaminated with up to 20% of ethyl fumarate and maleate.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04288610
Source datasetuspto-grants-1981_09
ORD IDord-5b673f6305924bb9bf9b5cee752d3e0d
Source noteuspto-grants-1981_09