HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl diazoacetate → Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl diazoacetate | HCID 12192 | — |
| Reactant | 1,3-Pentadiene, 1,1-dichloro-4-methyl- | HCID 108746 | — |
| Catalyst | Copper Sulfate | HCID 24462 | — |
| Product | Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, ethyl ester | HCID 101094 | — |
Reaction Steps
Thus, for example, in Pesticide Science (1974) 5, 791-799 it is shown that the reaction between ethyl diazoacetate and 1,1-dichloro-4-methylpenta-1,3-diene in the presence of copper sulfate to produce ethyl 2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropanecarboxylate, results in a product which is contaminated with up to 20% of ethyl fumarate and maleate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04288610 |
| Source dataset | uspto-grants-1981_09 |
| ORD ID | ord-5b673f6305924bb9bf9b5cee752d3e0d |
| Source note | uspto-grants-1981_09 |