Phosphoric Acid → Urea phosphoric acid

The process is very simple to carry out; starting with anhydrous ortho-phosphoric acid, which is crystalline at room temperature, a slight heating transforms the crystals into a clear liquid solution. In order to induce the spontaneous reaction with the solid urea, a preheating of the anhydrous ortho-phosphoric acid at 60°-90°C is preferred. After mixing with the solid urea, the reaction system has to be vigorously cooled in view of the exothermic reaction which takes place. The reaction is accomplished after a few seconds and dry crystalline urea phosphate formed in the reaction vessel is ready for use without any further operation. When starting with concentrated ortho-phosphoric acid, which has a concentration of over 90% H3PO4 (wt. per cent), the reaction according to the invention can be carried out in two ways. According to one preferable procedure the two reactants, in which the ortho-phosphoric acid (above 90% by wt. H3PO4) is previously preheated at 60°-90°C, are mixed. The water present in the initial ortho-phosphoric acid is expelled during the prior heating and exothermal reaction with the solid urea. By another procedure the initial concentrated ortho-phosphoric acid (above 90% H3PO4) is first transformed into the anhydrous form and thereafter reacted with the solid urea. The final product in both procedures was the same as in the case of anhydrous ortho-phosphoric acid, and containing only between 0.3% and 0.7% water.

1. customis crystalline at room temperature
2. temperaturea slight heating
3. customat 60°-90°C
4. temperatureto be vigorously cooled in view of the exothermic reaction which
5. waitThe reaction is accomplished after a few seconds

ORD record

ord-a744a9e316134e2a9551ceffffb00d3b

Source dataset

uspto-grants-1976_02

DOI

10.6084/m9.figshare.5104873.v1

Patent number

US03936501