Hexamethylenediamine → N-phenylstearyl hexamethylene diamine

HRID 1578428Notes

Reaction equation

HRID 1578428 reaction equation
[C:1]1([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24]Br)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[NH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][NH2:33]>C(O)C>[C:1]1([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][NH:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][NH2:33])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 16402HexamethylenediamineHCID 53680545HCID 53680545, compound

Product 1

HCID 86733042N-phenylstearyl hexamethylene diamine

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Following the procedure of Example XVI a solution of 15.8 grams (0.04 mole) of phenylstearyl bromide and 37.2 grams (0.32 mole) of hexamethylene diamine in 400 ml of ethanol was refluxed for three hours. After the same recovery procedure 15.2 grams (88.4% crude mass yield) of N-phenylstearyl hexamethylene diamine was obtained having the following analysis:

Workup

  1. temperaturewas refluxed for three hours

Sources & evidence

ORD record
ord-a40055875796432c81ab38d600664d83
Source dataset
uspto-grants-1976_02
Patent number
US03936503

Reaction notes

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