Hydrazine hydrate (1:1) → HCID 21559366, compound

HRID 1578513Notes

Reaction equation

HRID 1578513 reaction equation
[CH3:1][C:2]1[C:3]([CH3:12])=[CH:4][C:5]2[S:9][C:8]([NH2:10])=[N:7][C:6]=2[CH:11]=1.O.[NH2:14]N.Cl.NN>>[CH3:1][C:2]1[C:3]([CH3:12])=[CH:4][C:5]2[S:9][C:8]([NH:10][NH2:14])=[N:7][C:6]=2[CH:11]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 347572-Amino-5,6-dimethylbenzothiazoleHCID 115031Hydrazinium chloride

Product 1

HCID 21559366HCID 21559366, compoundYield 82%

Procedure

5,6-Dimethyl-2-aminobenzothiazole (5.0 g., 0.028 mole), 85% hydrazine hydrate (3.49 g.; 0.056 mole) and hydrazine monohydrochloride (1.99 g.; 0.028 mole) were reacted in the procedures of Example 1. 5,6-Dimethyl-2-hydrazinobenzothiazole was obtained in 82% yield, m.p. 223°-228°C. Assay (titration) 97.2%. Recrystallization from ethanol gave material melting 235°-237°C. (dec.).

Sources & evidence

ORD record
ord-a8f0ee5f4c3e45ccb0db4ff45d6baad2
Source dataset
uspto-grants-1976_02
Patent number
US03937714

Reaction notes

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