HCID 53647982, compound → HCID 54336752, compound

HRID 1578549Notes

Reaction equation

HRID 1578549 reaction equation
[Cl:1][C:2]([O:5][C:6]1[CH:7]=[C:8]([N+:12]([O-])=O)[CH:9]=[CH:10][CH:11]=1)=[CH:3][Cl:4].[H][H]>C(O)C.[Ni]>[Cl:1][C:2]([O:5][C:6]1[CH:7]=[C:8]([CH:9]=[CH:10][CH:11]=1)[NH2:12])=[CH:3][Cl:4]

Participants

5

Reactant 2

HCID 53647982HCID 53647982, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 54336752HCID 54336752, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 702EthanolSolvent

Procedure

Yield: 115 grams of 3-(1',2'-dichlorovinyloxy)-nitrobenzene 1 mole of the nitro-product was dissolved in 1liter of ethanol and was reduced by means of hydrogen in an autoclave at 60°C, after 5 grams of a Raney-nickel catalyst (R/50) had been added. The catalyst was then filtered off with suction, the ethanol was distilled off, and the residue was distilled in vacuo.

Workup

  1. filtrationThe catalyst was then filtered off with suction
  2. distillationthe ethanol was distilled off
  3. distillationthe residue was distilled in vacuo

Sources & evidence

ORD record
ord-71117df808e445c48dc3d4b1dba7cba0
Source dataset
uspto-grants-1976_02
Patent number
US03937726

Reaction notes

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