Ethanol → HCID 12210739, compound

HRID 1578679Notes

Reaction equation

HRID 1578679 reaction equation
[C:1]([C:9]1[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=1[C:11]([NH2:13])=[O:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C=O.[CH2:20]([OH:22])C.C([O-])([O-])=O.[K+].[K+]>O>[OH:22][CH2:20][NH:13][C:11](=[O:12])[C:10]1[CH:14]=[CH:15][CH:16]=[CH:17][C:9]=1[C:1](=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

6

Reactant 4

HCID 702EthanolHCID 712FormaldehydeHCID 11430Potassium CarbonateHCID 3486152-benzoylbenzamide

Product 1

HCID 12210739HCID 12210739, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 2.25g. (0.01 mole) of o-benzoylbenzamide, 4 ml. of aqueous formaldehyde solution (38%), 4 ml. of ethanol and 4 ml. of a solution of 1g. K2CO3 in 35 ml. water was refluxed for 20 hours. It was then allowed to cool and the crystalline product was filtered off and washed with water to yield 2.2g. (85%) of analytically pure material, m.p. 166/8°C.

Workup

  1. additionA mixture of 2.25g
  2. temperatureto cool
  3. filtrationthe crystalline product was filtered off
  4. washwashed with water
  5. customto yield 2.2g
  6. custom8°C.

Sources & evidence

ORD record
ord-eb4b737bab734e93ba1d92d32dc2a6c4
Source dataset
uspto-grants-1976_02
Patent number
US03939152

Reaction notes

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