Sodium → 4-(3-Hexenylthio)-7-nitro-2,5-bis(trifluoromethyl)-benzimidazole

HRID 1578720Notes

Reaction equation

HRID 1578720 reaction equation
Cl[C:2]1[C:10]2[NH:9][C:8]([C:11]([F:14])([F:13])[F:12])=[N:7][C:6]=2[C:5]([N+:15]([O-:17])=[O:16])=[CH:4][C:3]=1[C:18]([F:21])([F:20])[F:19].[Na].[CH2:23]([SH:29])[CH2:24][CH:25]=[CH:26][CH2:27][CH3:28]>>[CH2:23]([S:29][C:2]1[C:10]2[NH:9][C:8]([C:11]([F:14])([F:13])[F:12])=[N:7][C:6]=2[C:5]([N+:15]([O-:17])=[O:16])=[CH:4][C:3]=1[C:18]([F:21])([F:20])[F:19])[CH2:24][CH:25]=[CH:26][CH2:27][CH3:28]

Participants

4

Reactant 3

HCID 5360545SodiumHCID 540899513-Hexene-1-thiolHCID 1355549354-Chloro-7-nitro-2,5-bis(trifluoromethyl)benzimidazole

Product 1

HCID 544676254-(3-Hexenylthio)-7-nitro-2,5-bis(trifluoromethyl)-benzimidazole

Procedure

4-Chloro-7-nitro-2,5-bis(trifluoromethyl)benzimidazole is reacted with the sodium salt of 3-hexene-1-thiol to obtain 4-(3-hexenylthio)-7-nitro-2,5-bis(trifluoromethyl)-benzimidazole, m.w., 413.4.

Sources & evidence

ORD record
ord-dd6f246b053e46e8aa70713d0609bd02
Source dataset
uspto-grants-1976_02
Patent number
US03939166

Reaction notes

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