Sodium → HCID 21558550, compound

HRID 1578740Notes

Reaction equation

HRID 1578740 reaction equation
Cl[C:2]1[C:10]2[NH:9][C:8]([C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13])=[N:7][C:6]=2[C:5]([N+:18]([O-:20])=[O:19])=[CH:4][C:3]=1[C:21]#[N:22].[Na].[CH3:24][CH:25]([OH:30])[CH2:26][C:27]#[C:28][CH3:29]>>[CH3:24][CH:25]([O:30][C:2]1[C:10]2[NH:9][C:8]([C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13])=[N:7][C:6]=2[C:5]([N+:18]([O-:20])=[O:19])=[CH:4][C:3]=1[C:21]#[N:22])[CH2:26][C:27]#[C:28][CH3:29]

Participants

4

Reactant 3

HCID 5360545SodiumHCID 12908367Hex-4-yn-2-olHCID 135783935HCID 135783935, compound

Product 1

HCID 21558550HCID 21558550, compound

Procedure

4-Chloro-7-nitro-5-cyano-2-pentafluoroethylbenzimidazole is reacted with the sodium derivative of 4-hexyn-2-ol to obtain 4-(1-methyl-3-pentyn-1-yloxy)-7-nitro-5-cyano-2-pentafluoroethylbenzimidazole, m.w., 402.3.

Sources & evidence

ORD record
ord-55b5b3dcee974f37b967363c63c1de03
Source dataset
uspto-grants-1976_02
Patent number
US03939166

Reaction notes

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