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HRID1579000

反应详情

EQUATION

反应方程式

HRID 1579000 的结构方程式

REACTANTS

反应物

4
结构：OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O
HCID5793

未命名化合物

结构：CCCCCCBr
HCID8101

1-Bromohexane

C6H13Br

结构：CCCCCC[N+](=O)[O-]
HCID12589

1-Nitrohexane

C6H13NO2

结构：CN(C)[S+](N(C)C)N(C)C.O=N[O-]
HCID21557485

未命名化合物

PRODUCTS

生成物

1
结构：CCCCCCON=O
HCID6365123

Nitrous acid, hexyl ester

C6H13NO2

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC#N
溶剂HCID6342

Acetonitrile

C2H3N

PROCEDURE

实验过程

A 165-mg (1 mmole) sample of 1-bromohexane was added to 0.5 ml (1 mmole) of 2M tris(dimethylamino)sulfonium nitrite in acetonitrile. The course of the reaction was followed by glc analysis. No further reaction occurred after 15 min. Glc analysis showed that 1-nitrohexane and 1-hexyl nitrite were formed in a 70:30 ratio.

WORKUP

后处理

  1. customNo further reaction