HuagongsheHuagongshe Chemistry Print Report · For research reference only
D-Glucose → Nitrous acid, hexyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | D-Glucose | HCID 5793 | — |
| Reactant | 1-Bromohexane | HCID 8101 | — |
| Reactant | 1-Nitrohexane | HCID 12589 | — |
| Reactant | Tris(dimethylamino)sulfonium nitrite | HCID 21557485 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | Nitrous acid, hexyl ester | HCID 6365123 | — |
Reaction Steps
A 165-mg (1 mmole) sample of 1-bromohexane was added to 0.5 ml (1 mmole) of 2M tris(dimethylamino)sulfonium nitrite in acetonitrile. The course of the reaction was followed by glc analysis. No further reaction occurred after 15 min. Glc analysis showed that 1-nitrohexane and 1-hexyl nitrite were formed in a 70:30 ratio.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03940402 |
| Source dataset | uspto-grants-1976_02 |
| ORD ID | ord-b299314bb2084a96854535dde897a5ae |
| Source note | uspto-grants-1976_02 |