Trichloroacetyl chloride → HCID 21558133, compound

HRID 1579083Notes

Reaction equation

HRID 1579083 reaction equation
[Cl:1][C:2]([Cl:7])([Cl:6])[C:3](Cl)=[O:4].[CH2:8]([N:10]([CH2:13][CH3:14])[CH:11]=[O:12])[CH3:9]>C(N(CC)CC)C>[CH2:8]([N:10]([CH2:13][CH3:14])[C:11](=[O:12])[C:3]([C:2]([Cl:7])([Cl:6])[Cl:1])=[O:4])[CH3:9]

Participants

4

Reactant 2

HCID 6420Trichloroacetyl chlorideHCID 12051Diethylformamide

Product 1

HCID 21558133HCID 21558133, compound

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

The procedure of Example 1 was followed using 27g (0.15 mole) of trichloracetyl chloride and 45g (0.45 mole) of diethyl-formamide and 15g (0.15 mole) of triethylamine. Obtained following distillation was 14g 0f pure N,N-diethyl 3,3,3-trichloropyruvamide as a clear, colorless liquid: Bp 94°-96° (0.15 mm); ir (λmax, film) 5.7 (s), 6.1 (s), 6.8 (s), 6.9 (s), 9.4 (s), 12.1 (s) microns.

Workup

  1. customObtained
  2. distillationdistillation

Sources & evidence

ORD record
ord-6cc0c4c37d2745a5a1300a2e61f177a8
Source dataset
uspto-grants-1976_02
Patent number
US03940458

Reaction notes

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