Hydrogen Bromide → HCID 21567183, compound

HRID 1579138Notes

Reaction equation

[N+](C1C=CC=C2C=1C=CN=C2)([O-])=O.[CH3:14][C:15]1[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[CH:18]=[CH:17][N:16]=1.Br.[Cl:26][C:27]1[C:32]([OH:33])=[C:31]([Cl:34])[C:30]([Cl:35])=[C:29]([Cl:36])[C:28]=1[Cl:37]>>[Cl:26][C:27]1[C:32]([O-:33])=[C:31]([Cl:34])[C:30]([Cl:35])=[C:29]([Cl:36])[C:28]=1[Cl:37].[CH3:14][C:15]1[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[CH:18]=[CH:17][NH+:16]=1

Participants

Reactant 4

HCID 260Hydrogen Bromide

HCID 992Pentachlorophenol

HCID 155921-Methylisoquinoline

HCID 690855-Nitroisoquinoline

Product 1

HCID 21567183HCID 21567183, compound

Procedure

was prepared by the procedure of Example 29 hereinabove, except that the 5-nitro-isoquinoline of that example was replaced by 1-methyl-isoquinoline and the hydrogen bromide was replaced by an ethanolic solution of pentachlorophenol, to yield 1-methyl-isoquinolinium pentachlorophenoxide melting over the range 148° - 150°C.

Sources & evidence

ORD record: ord-0676fef7e4e84992862e0ed67f4101f6
Source dataset: uspto-grants-1976_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03930837

Reaction notes

Loading…