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HRID1579429

反应详情

EQUATION

反应方程式

HRID 1579429 的结构方程式

REACTANTS

反应物

3
结构：CC(=O)O
HCID176

Acetic Acid

C2H4O2

结构：[N-]=[N+]=[N-].[Na+]
HCID33557

未命名化合物

结构：CC(=O)O[C@]1(C(C)=O)CC[C@H]2[C@@H]3[C@@H](OS(C)(=O)=O)[C@@H](OS(C)(=O)=O)C4=CC(=O)CC[C@]4(C)[C@H]3CC[C@@]21C
HCID86732876

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@]1(C(C)=O)CC[C@H]2[C@@H]3C=C(N=[N+]=[N-])C4=CC(=O)CC[C@]4(C)[C@H]3CC[C@@]21C
HCID86732875

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

In a manner similar to that described in Example 6C, treat 6β,7β-dimethanesulfonyloxy-17α-acetoxy-4-pregnene-3,20-dione with sodium azide in aqueous methanol in the presence of acetic acid. Isolate and purify the resultant product in a manner similar to that described to obtain 6-azido-17α-acetoxy-4,6-pregnadiene-3,20-dione.

WORKUP

后处理

  1. customIsolate
  2. custompurify the resultant product in a manner similar to