HRID1579430

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID33557

未命名化合物

结构：CC(=O)O[C@]1(C(C)=O)CC[C@H]2[C@@H]3[C@@H](OS(C)(=O)=O)[C@@H](OS(C)(=O)=O)C4=CC(=O)C=C[C@]4(C)[C@H]3CC[C@@]21C

HCID18594205

未命名化合物

PRODUCTS

生成物

结构：CC(=O)O[C@]1(C(C)=O)CC[C@H]2[C@@H]3C=C(N=[N+]=[N-])C4=CC(=O)C=C[C@]4(C)[C@H]3CC[C@@]21C

HCID86732877

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

In a manner similar to that described in Example 1D, treat 6β,7β-dimethanesulfonyloxy-17α-acetoxy-1,4-pregnadiene-3,20-dione with sodium azide in dimethylformamide. Isolate and purify the resultant product in a manner similar to that described in Example 1D to obtain 6-azido-17α-acetoxy-1,4,6-pregnatriene-3,20-dione.

WORKUP

后处理

customIsolate
custompurify the resultant product in a manner similar to