Diethylamine → HCID 131709892, compound

HRID 1579833Notes

Reaction equation

HRID 1579833 reaction equation
[CH2:1]([NH:3][CH2:4][CH3:5])[CH3:2].[Cl:6][CH:7]([C:11]1[CH:20]=[CH:19][C:18]2[C:13](=[CH:14][CH:15]=[C:16]([O:21][CH3:22])[CH:17]=2)[CH:12]=1)[C:8]([OH:10])=[O:9]>CCCCCC>[CH2:1]([NH2+:3][CH2:4][CH3:5])[CH3:2].[Cl:6][CH:7]([C:11]1[CH:20]=[CH:19][C:18]2[C:13](=[CH:14][CH:15]=[C:16]([O:21][CH3:22])[CH:17]=2)[CH:12]=1)[C:8]([O-:10])=[O:9]

Participants

4

Reactant 2

HCID 8021DiethylamineHCID 21569134HCID 21569134, compound

Product 1

HCID 131709892HCID 131709892, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Anhydrous diethylamine (0.11 moles) is added dropwise to a stirred solution of α-chloro-6-methoxy-2-naphthylacetic acid (0.10 moles) in 100 ml. of n-hexane at 0°C. The precipitate is collected on a filter, washed with n-hexane, and dried in a vacuum desiccator to obtain α-chloro-6-methoxy-2-naphthylacetic acid, diethylammonium salt.

Workup

  1. customat 0°C
  2. customThe precipitate is collected on a filter
  3. washwashed with n-hexane
  4. customdried in a vacuum desiccator

Sources & evidence

ORD record
ord-4b75e2bc0fec4df499e80f416c4606fb
Source dataset
uspto-grants-1976_01
Patent number
US03931269

Reaction notes

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