Ethanol → Cyclohexanone, 2-[2-(3,4-dichlorophenyl)-2-oxoethyl]-

HRID 1579899Notes

Reaction equation

HRID 1579899 reaction equation
N1([C:6]2[CH2:11][CH2:10][CH2:9][CH2:8][CH:7]=2)CCCC1.[Cl:12][C:13]1[CH:14]=[C:15]([CH:20]=[CH:21][C:22]=1[Cl:23])[C:16](=[O:19])[CH2:17]Br.C([OH:26])C>>[Cl:12][C:13]1[CH:14]=[C:15]([CH:20]=[CH:21][C:22]=1[Cl:23])[C:16](=[O:19])[CH2:17][CH:7]1[CH2:8][CH2:9][CH2:10][CH2:11][C:6]1=[O:26]

Participants

4

Reactant 3

HCID 702EthanolHCID 707681-Pyrrolidino-1-cyclohexeneHCID 2447512-Bromo-1-(3,4-dichlorophenyl)ethanone

Product 1

HCID 12270332Cyclohexanone, 2-[2-(3,4-dichlorophenyl)-2-oxoethyl]-

Procedure

(0.19 mole) of 1-pyrrolidino-1-cyclohexene and 51.2 g. (0.19 mole) of 3,4-dichlorophenacyl bromide by the method described in Example 39a gave 32.6 g. (60%) of crystals, m.p. 78°-79° (from ethanol).

Workup

  1. customgave 32.6 g

Sources & evidence

ORD record
ord-6c68ce6c129c4a1f9990ef8f4d6453e8
Source dataset
uspto-grants-1976_01
Patent number
US03931407

Reaction notes

Loading…