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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1579930Generated: October 31, 2026

N-phenyl-1-(4-phenylphenyl)methanimine → 2-{4-[2-([1,1'-Biphenyl]-4-yl)ethenyl]phenyl}-5,7-dichloro-1-benzofuran

https://huagongshe.com/reaction/1579930

Reaction equation

Participants

RoleNameHCIDCharge
ReactantN-phenyl-1-(4-phenylphenyl)methanimineHCID 291033—
Reactant5,7-Dichloro-2-(4-methylphenyl)-1-benzofuranHCID 21496036—
ReactantPotassium tert-butoxideHCID 23665647—
Product2-{4-[2-([1,1'-Biphenyl]-4-yl)ethenyl]phenyl}-5,7-dichloro-1-benzofuranHCID 54411368—

Reaction Steps

Following the procedure given in Example 1b equimolar quantities of the above named 5,7-dichloro-2-(p-tolyl)benzofuran and 4-phenylbenzalaniline were interacted in the presence of potassium tert.-butoxide to give 5,7-dichloro2-{4-[2-(4-biphenylyl)vinyl]phenyl}benzofuran which, following recrystallization from chlorobenzene, melted at 258°-260° C. The wavelength of maximum excitation of this compound was 375 nm., and the wavelength of maximum emission was 431 nm.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS03932301
Source datasetuspto-grants-1976_01
ORD IDord-6d3c01cde329492b82966f7d9c04f748
Source noteuspto-grants-1976_01